Arsenal were the only club from the English Premier League's big six to make a significant signing as an underwhelming transfer deadline day entered its last few hours.
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The Gunners have bolstered their defence by signing Southampton's 26-year-old Portugal right-back Cedric Soares on loan until the end of the season.
Manchester City defender Angelino, who has made 12 appearances for Pep Guardiola's side in all competitions this season, has joined Bundesliga high-flyers RB Leipzig on loan.
The German side have have the option to buy Angelino for STG 25.2 million in the summer, it is understood.
Elsewhere, Jurgen Klopp and Frank Lampard have ruled out any further activity before the window shuts at 11pm local time, while Real Madrid dismissed suggestions Gareth Bale could be set for a big-money return to Tottenham.
Lampard also quashed speculation that Olivier Giroud was set to leave Chelsea, possibly to make a shock move to London rivals Spurs.
Lampard said: "Olivier Giroud in this window has been incredible as a professional and as a man. We know there has been interest... will he leave? No."
Manchester United brought in Nathan Bishop from League One strugglers Southend, but United boss Ole Gunnar Solskjaer also said he expected no further business. A possible move for Bournemouth striker Joshua King reportedly appeared to be off.
Edinson Cavani, another striker linked with United and also Chelsea, will remain at Paris St Germain until at least the summer.
Cavani's expected move to Atletico Madrid fell through and PSG boss Thomas Tuchel has confirmed the Uruguayan could feature for his side in Saturday's home Ligue 1 clash with Montpellier.
West Ham are hoping to complete deal for Hull striker Jarrod Bowen, while Wolves are expected to sign off their move for Rochdale defender Luke Matheson.
Sheffield United made their fourth signing of the window as they brought in Dutchman Richairo Zivkovic on loan from Chinese club Changchun Yatai.
Aston Villa are set to sign striker Borja Baston on a free transfer from Championship club Swansea, the PA news agency understands.
Wigan defender Antonee Robinson saw his dream move to AC Milan collapse in heartbreaking circumstances.
Former Liverpool midfielder Emre Can, who left Anfield for Juventus in 2018, has joined Bundesliga side Borussia Dortmund on loan until the end of the season with a view to a permanent move.
Australian Associated Press
